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Archival gel ink for my Sensa Stylist?
Today I picked up a Sensa Stylist pen, a large ergonomic heavy pen. I
am quite happy with it, but one of the things I wanted to check on was the "Archival" quality of the Parker gel refills I am using with it. I understand that the Pilot Dr. Grip style rollerball ink is "archival quality" even though I haven't seen a real duration on this. I was wondering if the Parker ink I am using in the Sensa is of the same quality or not. What I had read is that gel ink in general is archival quality, but I would like to make sure. The idea of writing little bits of nonsense that can be discovered and read five hundred years from now gives me a warm fuzzy. I read one negative review of the parker gel refills, but I wanted to get some more opinions. If anyone knows of a truely "archival" quality ink that fits inside a Sensa Stylist pen, please let me know, or of the Parker Gel is fine, I will just stick with what I have. Thanks! Mike Shea |
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In article ,
Mike Shea wrote: What I had read is that gel ink in general is archival quality, but I would like to make sure. No, it's certainly not. Some _may_ qualify, often the black ones, but some are very easy to fade to nothing. I've made some informal tests, but only light and water, real archival quality is more demanding (and requires archival quality paper too): http://www.canit.se/%7Egriffon/writing/#misc If anyone knows of a truely "archival" quality ink that fits inside a Sensa Stylist pen, please let me know, or of the Parker Gel is fine, I will just stick with what I have. You'll have to go with ballpoint refills which are actually certificated as archival or at least marked "for documents". -- Urban Fredriksson http://www.canit.se/%7Egriffon/ To get rid of an enemy, make him a friend. |
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"Mike Shea" wrote in part: | Today I picked up a Sensa Stylist pen, a large ergonomic heavy pen. I | am quite happy with it, but one of the things I wanted to check on was | the "Archival" quality of the Parker gel refills I am using with it. They are NOT archival. They are NOT even close. And if a refill or package is NOT marked archival, you can be assured it is NOT. This is a great marketing factor, were it true it would be listed. The slightest bit of water and the Parker gels are GONE. | What I had read is that gel ink in general is archival quality, but I | would like to make sure. Not even remotely true. Some gel inks are. The most notable illustration of the differences in gel ink in my book is that Pilot G2 05's and 07's are NOT archival whilst the similar looking Zebra Sarasa gel pens ARE. The aforesaid Pilots are not even water resistant! | The idea of writing little bits of nonsense | that can be discovered and read five hundred years from now gives me a | warm fuzzy. Not unless you also use archival paper. Otherwise, the paper may disappear long before the ink. Even then, ideal storage conditions are required. More likely, about 5000 seconds, or 500 days, or 20 years if you are really exceptional, after your demise, your loved ones will toss your scribblings in the nearest garbage can or sell them at a rummage sale. Unless, of course, you are Mr. King of mystery fame. Then they will sell them and take trips to Paris and such. And the cycle will repeat with the new buyers, until eventually people say Stephen who? | | I read one negative review of the parker gel refills, but I wanted to | get some more opinions. They are nice, but run out of ink quickly. The red starts out being reddish tan and soon becomes reddish brown, at least in my experience. I have gone back to using Pelikan's international style ballpen refills in my Parkers. | | If anyone knows of a truely "archival" quality ink that fits inside a | Sensa Stylist pen, please let me know, or of the Parker Gel is fine, I | will just stick with what I have. No archival gels fit the Parker ballpens, to my knowledge. Not yet. Given how small the barrel is, perhaps not ever. john cline ii who hopes that helps |
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Mike Shea wrote:
Today I picked up a Sensa Stylist pen, a large ergonomic heavy pen. I am quite happy with it, but one of the things I wanted to check on was the "Archival" quality of the Parker gel refills I am using with it. I understand that the Pilot Dr. Grip style rollerball ink is "archival quality" even though I haven't seen a real duration on this. I was wondering if the Parker ink I am using in the Sensa is of the same quality or not. What I had read is that gel ink in general is archival quality, but I would like to make sure. The idea of writing little bits of nonsense that can be discovered and read five hundred years from now gives me a warm fuzzy. I read one negative review of the parker gel refills, but I wanted to get some more opinions. If anyone knows of a truely "archival" quality ink that fits inside a Sensa Stylist pen, please let me know, or of the Parker Gel is fine, I will just stick with what I have. Thanks! Mike Shea hm i think you need to make your own, try:- Four gallons of linseed oil; two of cocoa-nut oil; one gallon of good molasses; five pounds of loaf sugar; two pounds each of ground sacre seed, ground cotton seed, Venice turpentine, ivory black, Antwerp black, finely powdered burnt horns, tartar, pulverised gum-kino, and anacardium nuts; four pounds each of very finely powdered charcoal, dried bullocks' blood and gum arabic; one pound each of solution of caoutchouc, parchment shavings, powdered seed lac and Indian borax; and three pounds each of Aleppo galls, pomegranate, peel, fine glue and walnut skins - are mixed and boiled in a large iron caldron. On the commencement of ebullition, the mixture is ignited with a bar of red-hot iron, and the smoke which is liberated is received into a capacious inverted cone made of the best sheet iron. As soon as the whole of the oil is consumed, the carbon which adheres to the cone is collected and carefully preserved. The residuum is then removed from the boiler and rubbed down to an impalpable powder. One pound of carbon collected from the cone and a similar quantity of the prepared residuum are then mixed with a quart for the best French vinegar, two gallons of hot water and four ounces of gum-lac and these ingredients are boiled for ten minutes, when a pound of Aleppo galls in fine powder and two pounds of logwood chips are added. The mixture is stirred until cold and is then poured into large flat pans exposed to the atmosphere for three weeks.2524Mitchell, C, Inks: their composition and manufacture, 1937 25 Family Tree 1989, vol. 5, no. 6, p. 32 ---------------------------------------------------------------------------- ---- Page 16 14 Colouring-Iron Gall InksThe use of dyestuffs (usually of a blue colour) such as logwood22, or indigo23, to strengthen the colour of the freshly made iron-gall ink, was practised to a small extent during the 18th century. The added dye has little or no influence on the fastness of writing to washing, but gives an agreeably bold colour. William Lewis, a mid-eighteenth century English scientist, experimented with the addition of various berry juices, but found them detrimental to the colour of the writing when exposed to sunlight. Logwood extract was found most satisfactory for this purpose but was gradually replaced by other dyes. The use of indigo for ink, though described in 1770, was only introduced into England by Dr Henry Stephens in 1836. During the nineteenth century, advances in the science of chemistry, and the improved availability of dyes, allowed colouring alternatives to be developed. One of the first ink factories was set up in 1834 to cater for the new demand, and its proprietors, Messrs Stephens, advertised their new patent writing fluids in bold terms in Robson's London Directory for 1834: This iron-gall-dye mixture became the popular Stephens blue-black ink.... an extract of 42 parts Alleppo galls and 3 parts of madder in 120 parts of water, mixed with 11/5 parts of indigo solution, 5 parts of ferrous sulphide, and 2 parts of metallic iron, dissolved in crude acetic acid.2826Madder is obtained from the root of the madder plant Rubia tinctorum. Madder was first extracted by the Egyptians and used for dyeing textiles, it does not appear to have been important as a lake pigment until the seventeenth or eighteenth century. 27Alzarine, in its true definition, is an orange-red dye formerly prepared from madder. It is now produced synthetically, the adjective referring to any of a number of dyes similar to alizarin. It should not be confused with the ink synthesised by Leonardi in 1856 from indigo, to which he gave the name 'Alizarin'. 28 Mitchell, C, Inks: their composition and manufacture, 1937 p. 130 ---------------------------------------------------------------------------- ---- Page 17 15 During the nineteenth century there was much experimentation and complex formulations of ink were tried. There are many recipes which consist of carbon, iron gall and logwood and an example of the complexity of some of the recipes is given by the following one found in Muspratt's Chemistry published in 1860. If you go through this recipe you will find that it is basically a mixture of the three types of ink described above, with some resin added to make the ink waterproof. It is unlikely that this ink ever went into mass production but it gives an example of Victorian ingenuity in attempting to produce "better" quality inks. Unoxidised Gall InksUntil the end of the 18th century inks were largely fluids which were more or less oxidised before use, at which point a r a d i c a l change came about in the method of manufacture. The new process consisted in protecting the ink from oxidation as far as possible, so that the formation of the insoluble pigment would take place within the fibres of the paper. In addition indigo was added to give the fluid a provisional colour. An unoxidised ink of this type was patented by Leonhardi of Dresden, in Hanover, in 1856 when a small proportion of madder26was incorporated in addition to the indigo, hence the term "alizarine"27which had been accepted as a descriptive title for this type of ink. 29 An ink without any extra acid added, known as a 'non-acid' iron ink, was first produced in 1908 by Silberman and Ozorovitz of Rumania. The new ink, composed of iron, ammonia and gallic acid, is technically known as diammonium hydroxyferrugallate, and is less corrosive that the traditional iron-gall ink. However this gallic acid lacked 'body' and did not penetrate the fibres of the paper so readily as acidified gallotannic inks, so was never successfully marketed. 30 Sodium or potassium hydroxide, or an alkaline solution of potassium carbonate from the leaching of wood ash. ---------------------------------------------------------------------------- ---- Page 18 16 Leonhardi subsequently omitted the madder as superfluous, making the ink alzarine free, but the more suitable name of "isatin" inks never met with popular acceptance. Owing to the absence of gum in the recipe, the inks flow more readily from the pen, and are less liable to clog. However they did not suit the new steel pens nibs as the presence of free acid in considerable proportions rapidly corroded the nib.29 Other Types of Black InkSepiaSepia was used first by the Romans, but its greatest popularity was between 1780 and the end of the nineteenth century. It is the black or dark brown secretion from the "ink sac" of the common cuttlefish or squid, sepia officinalis, and other allied cephalopods. Genuine sepia ink is an extract obtained from the mollusc containing mineral and organic substances which are insoluble in water. For preparation the ink sacs are removed, dried, pulverised and boiled in a solution of lye30. The extract, which is dissoved in the lye, is then precipitated out by the addition of hydrochloric acid. It is washed, dried at a low temperature, ground very finely with gum arabic and made into cakes. The colouring matter is a complex nitrogenous compound, which, in thin washes, is fugitive to light. Bistre31 Other examples are brasil wood (Caesalpinia spp.) and madder roots (shrub Rubia Tinctorium) for the red dyes and pigments; logwood (Haematoxylon campechianum) for purple-red colours; saffron (Crocus sativus) for yellow dyes; woad (from the plant Isatis tinctoria) for indigo, the blue dye-stuff.32 Other examples are the egg-bearing kermes insect (Coccus ilicis) for the pink dye and pigment known as kermes; larvae of the insect Coccus lacca, for the red dyestuff known as gum lac. 33 Other examples include the mineral earth Crocus Martis for the yellow pigment known as saffron of Mars; Red clays containing iron oxides for red ochres etc.; colloidal forms of gold,, made by reducing gold salts with tin and iron salts, which gave the purple cassius; verdigris, a hydrated copper acetate, made by reacting copper or brass with vinegar, for green colours; coppers sulphate (blue stone) for blue colours; iron salts dissolved in beer (beer black) for blacks. ---------------------------------------------------------------------------- ---- Page 19 17 Bistre is the yellowish brown tarry soot collected from the burning of wood (most commonly beech) very close to a flame. The colour varies from saffron yellow to b r o w n -b l a c k depending upon the source and treatment of the raw material. Its precise history of usage is unclear; its use probably began during the fourteenth century although it was only commonly seen from the eighteenth century. It is composed of carbon black and a high proportion of tars; these are complex aromatic hydrocarbons. The tars oxidise over time and there may be a shift in tone of the ink. Although both these inks have been used as writing inks they were (and are) more popular as drawing inks. Coloured Writing InksColoured inks for writing and painting were available from the earliest times, the most common being red, green, purple and yellow. This broad range of coloured inks and paints was the outcome of widespread geographic experimentation using local materials together with inorganic chemical substances, linked with the spread of chemical knowledge. Colours and pigments might be obtained from plant sources, such as logwood (Haematoxylon campechianum) for purple-red colour31; animal sources, such as the egg bearing Coccus cacti beetle which was used for the Take urine and keep it for a long while and afterwards make it boil until half of it is evaporated upon a slow and clear fire, skimming it continually until it is perfectly purified. Then strain it through a linen cloth and put 4 lbs of it into a glazed jar of the said urine and 1 lb of raw lac well ground, and add to it sufficient quantity of alumine zuccarion (alum which has been heated and ground with rose water, sugar and white of egg and allowed to harden on standing) and put it by and keep it for use 34.34 Reed, R, Ancient skins, parchments and leathers, 1972. p. 16235Aniline is an oily liquid, moderately soluble in water and obtained by the reduction of nitrobenzene derived from coal or coal tar, although it was first obtained by destructive distillation of indigo. Its name is taken from the specific name of the indigo-yielding plant Indigofera anil (Indigofera suffruticosa). It is toxic, colourless when freshly made, and turns a dark yellow in the presence of oxygen. 36A blue black dye stuff. ---------------------------------------------------------------------------- ---- Page 20 18 crimson dye known as cochineal (introduced into Europe from Mexico in the sixteenth century)32; or from inorganic mineral and clay substances, such as lapis lazuli which when ground gave the blue pigment ultramarine or azure33: Most colours were ground in the same way as the black colourants, first milled dry and then ground in the form of a paste with water. Red ink was greatly used in medieval manuscripts for headings, running titles and initials, for rubrics (hence the word) in liturgical manuscripts, and for red-letter days (hence that term also) in Calendars. An example of a recipe to make lake (red dye from insect larvae known as gum lac) as follows: Aniline InksA major development in the manufacture of ink was the use of aniline35dyes, not merely for coloured writing fluids but also for taking the place of indigo in the black inks. In 1856 William Henry Perkins, an English chemist, discovered the synthetic dye mauveine. It came into general use as a base for synthetic or artificial dyes in 1856 with the advent of fuchsines, dyestuffs that dissolve in water to form violet and Bismarck-brown solutions. Unfortunately, early aniline inks were very sensitive to exposure to light and air. However, the higher quality of the modern varieties gives them greater strength and stability. The first British patent for the employment of these aniline dyes as ink was granted to Croc of Paris in 1861 and it was followed by several others. Thus under the name ---------------------------------------------------------------------------- ---- Page 21 19 If inks are mixed indiscriminately, precipitates can form that cause the fountain pen to clog. For this reason, pen manufacturers tend to recommend their own inks and caution users about mixing ink colours and brands. The first satisfactory free-flowing ball-point pen inks were based on a solution of dye in oleic acid with special oils and resins added to give the pen proper flow characteristics (c. 1945)37. These inks had a common problem - they never quite dried on the paper and consequently would offset from one paper to another. Also the dyes used in these oil-based inks, as they were called, had very poor resistance to light, particularly direct sunlight. Modern ball-point inks are the result of the development of lightfast organic dyes and improved selection and blending of solvents. These inks have a viscosity of about 10,000 times that of water, are quick drying, do not smear, have good to excellent lightfastness, and will remain legible under proper storage conditions for the life of the paper on which they are written. Typically, modern ball-point inks may contain up to ten ingredients, each serving a specific purpose. The final product is a very expensive fluid as compared with aqueous ink, but gram for gram it will produce many times more writing. Normal dye inks, formerly called aniline inks, are usually aqueous solutions of anionic dyes (acidic dyes). Because of this composition they are also easily washed out. Of the usual hues (blue, black, green and red), the blue is predominant, and the modern fountain-pen inks with the designation Royal Blue account for about 95% of the total ink market consumption. The proprietary blue ink types usually contain triarylmethane dyes. The inks that have better light- and waterfastness are based on water-soluble anionic direct dyes, such as phthalocyanine dyes. 37The first patent for a ball-type dispenser was issued on October 30th 1888 to John. H. Loud, an American. Loud's pen was designed for marking on rough surfaces and not for handwriting, but its operation was quite similar to todays pen. The improved methods for grinding and measuring balls for ball bearings, developed during World War II, proved adaptable to ball-points and Lazlo Biro, a Hungarian living in Argentina, was the first to make a satisfactory ball-point pen. He was granted a patent for his development in 1944. ---------------------------------------------------------------------------- ---- Page 22 20 Standards for Writing InksThere have been two main issues in setting standards for modern writing inks. The first is that of technological change. Since 1945, traditional iron gall inks have been replaced by dye-based inks. Fountain pens have replaced dip pens which, in their turn, have been superseded by ball point pens and, more recently, by felt and roller ball pens. The second problem is one of enforcement. It is possible to specify the use of permanent inks for formal records38, such as registers of births, but it is impossible, and unnecessary, to insist that individuals use such inks for their ordinary day-to-day writing. Attempts to produce standards for writing inks date back to the 1879 Prussian law that only iron-gall ink should be used officially. In 1888, rules for testing inks were published and these were revised in 1912. These (Prussian) regulations have profoundly influenced later standards and most standards for inks for use in dip pens and fountain pens appear to be based on them. 38 BS 3484:1991 Specification for Blue-black record inks. ---------------------------------------------------------------------------- ---- Page 23 21 Barrow, W. J.Manuscripts and Documents, their De-terioration and RestorationUniversity of Virginia Press, Char-lottesville, Virginia (1955) Bologna, Giulialluminated Manuscripts: The Book be-fore GutenbergThames and Hudson, London (1988)Clarke, AeliAn Introduction to Drawing Materials, Binders and PigmentsChemistry Dept. (conservation) Sum-mer Short Courses (1995) Camberwell College of Arts, London SE5Collings, T. J.The Creation and Care of Documents, part two; Parchment, Vellum and InkFamily Tree (April 1989)Crespo, Carmen and Vinas, VicenteThe Preservaion and Restoration of Pa-per Records and Books: a RAMP study with guidelines UNESCO, Paris (1984)De Hamel, Christopher Medieval Craftsmen: Scribes and Illumi-natorsBritish Museum Press, London 1992Harley, R.DArtist` Pigments c.1600-1835ButterworthsFairbank, A. The Story of Handwriting: Origins and DevelopmentFaber & Faber Ltd. (1970)Gettens, R. J. and Stout, G. L.Painting Materials: a short encyclopediaDover Publications, Inc., New York (1966)Hector, L. C.The Handwriting of English DocumentsEdward Arnold Ltd. (1958)Jackson, DonaldThe Story of WritingBarrie & Jenkins Ltd., London (1981)Jennett, SeanThe Making of Books, 5th edition Faber & Faber Limited (1973) Mitchell, C. AinsworthInks: their Composition and Manufac-ture including Methods of Examination and a full list of British patents, 4th edi-tionCharles Griffin & Company Limited, London (1937)Reed, R.Ancient skins, parchments and leathersSeminar Press, London and New York (1972)Thomas, D. L.Survey onNnational Standards on Pa-perand Ink to be used by the Admini-stration for Records Creation: a RAMP study with guidelinesEncyclopedia Bri-tanniaUNESCO, Paris (1987)Whalley, Muriel E.The Permance of InksResearch Plans & Publications Section, National Research Council of Canada, Ottowa November 1939 NRC No 880SELECTED BIBLIOGRAPHY five pounds of loaf sugar; two pounds each of ground sacre seed, ground cotton seed, Venice turpentine, ivory black, Antwerp black, finely powdered burnt horns, tartar, pulverised gum-kino, and anacardium nuts; four pounds each of very finely powdered charcoal, dried bullocks' blood and gum arabic; one pound each of solution of caoutchouc, parchment shavings, powdered seed lac and Indian borax; and three pounds each of Aleppo galls, pomegranate, peel, fine glue and walnut skins - are mixed and boiled in a large iron caldron. On the commencement of ebullition, the mixture is ignited with a bar of red-hot iron, and the smoke which is liberated is received into a capacious inverted cone made of the best sheet iron. As soon as the whole of the oil is consumed, the carbon which adheres to the cone is collected and carefully preserved. The residuum is then removed from the boiler and rubbed down to an impalpable powder. One pound of carbon collected from the cone and a similar quantity of the prepared residuum are then mixed with a quart for the best French vinegar, two gallons of hot water and four ounces of gum-lac and these ingredients are boiled for ten minutes, when a pound of Aleppo galls in fine powder and two pounds of logwood chips are added. The mixture is stirred until cold and is then poured into large flat pans exposed to the atmosphere for three weeks. see http://www.pro.gov.uk/about/preserva...ritinginks.pdf jolyon |
#5
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Jolyon Wright wrote:
Four gallons of linseed oil; two of cocoa-nut oil; one gallon of good loads of stuff sorry - I didnt mean to send *all* that stuff; grr. computers jolyon |
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